Rock-salt Ti1 −xO → rutile TiO2−x transformation twinning via pulsed laser deposition – implications for the dense (hkl)-specific phase change and optoelectronic properties
CrystEngComm, 2024, Advance Article DOI: 10.1039/D3CE01091K, PaperChang-Ning Huang, Jian-Yu Chen, Yu-Xuan Lin, Pouyan Shen The R + r intimate intergrowth was found to form a butterfly twin following the optimum crystallographic orientation relationship [101]R//[11 ̄]r by the close-packed ( ̄11)R and (011)r planes as the twin boundary and phase interface, respectively. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - CrystEngComm latest articles)
Source: RSC - CrystEngComm latest articles - March 14, 2024 Category: Chemistry Authors: Chang-Ning Huang Source Type: research

Synthesis of an iron-based metal –organic framework with octahedral cages for the selective capture of sulfur hexafluoride
CrystEngComm, 2024, Advance Article DOI: 10.1039/D4CE00041B, PaperHao Wang, Le Shi, Honghao Cao, Zhangyi Xiong, Si Ma, Jun Pan, Zhijie Chen An iron-based metal –organic framework with octahedral cages for the effective capture of sulfur hexafluoride. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - CrystEngComm latest articles)
Source: RSC - CrystEngComm latest articles - March 13, 2024 Category: Chemistry Authors: Hao Wang Source Type: research

A Zwitterionic Salt-Cocrystal: In-Vitro Insights from Niraparib Tosylate, an Anti-Cancer Drug
CrystEngComm, 2024, Accepted Manuscript DOI: 10.1039/D4CE00114A, PaperRamesh Reddy Mudda, Ramesh Devarapalli, Arijit Das, Pullareddy Lakkireddy, Chilla Malla Reddy, Ramanaiah Chennuru Niraparib is an anti-cancer drug marketed as a tosylate monohydrate salt (brand name ZEJULA). Although it was approved by the USFDA and the European Union in 2017, niraparib tosylate is... The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - CrystEngComm latest articles)
Source: RSC - CrystEngComm latest articles - March 13, 2024 Category: Chemistry Authors: Ramesh Reddy Mudda Source Type: research

Facile syntheses, structures and photocatalytic properties of 3-D iodoargentate frameworks derived from TM-flexible-amino-ligand templates
CrystEngComm, 2024, Accepted Manuscript DOI: 10.1039/D4CE00247D, PaperYan Gao, Xiao Yang, Taohong Ren, Dingxian Jia Three-dimensional iodoargentate hybrids [Co(en)3(Ag2I4)]n (1), [Fe(en)3(Ag2I4)]n (2) (en = ethylenediamine) and [Co(dien)2(Ag2I4)]n ∙nH2O (3) (dien = diethylenetriamine) were prepared in C2H5OH solvent via a one-step reaction under solvothermal conditions. In compounds... The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - CrystEngComm latest articles)
Source: RSC - CrystEngComm latest articles - March 13, 2024 Category: Chemistry Authors: Yan Gao Source Type: research

Influence of Mo concentration on the structural and electrochemical properties of double-doped Mo –Co–Ni3S2/NF composites
CrystEngComm, 2024, Advance Article DOI: 10.1039/D3CE01246H, PaperMuhammad Shoaib, Fen Qiao, Xiangchao Xu, Taihang Zhou, Yanzhen Liu The precursor chemical powders were mixed in compliance with the stoichiometric ratio in 25 ml of deionized water. Following the immersion of nickel foam in the solution, the autoclave was heated at 120 °C for 12 h. Subsequently, NF underwent the sulfuration process. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - CrystEngComm latest articles)
Source: RSC - CrystEngComm latest articles - March 12, 2024 Category: Chemistry Authors: Muhammad Shoaib Source Type: research

Gefitinib salt/cocrystal with phenolic acids as promising solid −state approach to improve solubility
CrystEngComm, 2024, Accepted Manuscript DOI: 10.1039/D4CE00039K, Paperyao zou, xin meng, Baoxi Zhang, Hongmei Yu, Guorong He, Ningbo Gong, Yang Lv, Guanhua Du To employ crystal engineering for the design and synthesize of a series of novel salts/cocrystals incorporating phenolic acids, aiming to modulate the solubility of Gefitinib (GEF), a multifunctional antineoplastic drug.... The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - CrystEngComm latest articles)
Source: RSC - CrystEngComm latest articles - March 12, 2024 Category: Chemistry Authors: yao zou Source Type: research

Fabrication of BiVO4 submicron rod photoanode through phase transition assisted by Mo doping
CrystEngComm, 2024, Accepted Manuscript DOI: 10.1039/D4CE00074A, PaperShuang Zhao, Haipeng Zhang, Zhaoqi Wang, Difei Xiao, Xianbin Xu, Peng Wang, Zhaoke Zheng, Yuanyuan Liu, Ying Dai, Hefeng Cheng, Zeyan Wang, Baibiao Huang The contradiction between the optical absorption depth and carrier diffusion length has emerged as a significant problem constraining the performance of BiVO4 photoanodes. Fabricating a one-dimensional (1D) structure is considered... The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - CrystEngComm latest articles)
Source: RSC - CrystEngComm latest articles - March 12, 2024 Category: Chemistry Authors: Shuang Zhao Source Type: research

The photomechanical bending and photosalient effect of flexible crystals of an acylhydrazone
CrystEngComm, 2024, Advance Article DOI: 10.1039/D3CE01321A, CommunicationPragyan J. Hazarika, Poonam Gupta, Suryanarayana Allu, Naba K. Nath Elastically flexible single crystals of an acylhydrazone derivative displayed photosalient effect preceded by photomechanical bending, demonstrating their utilisation for the design of multi-performance materials. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - CrystEngComm latest articles)
Source: RSC - CrystEngComm latest articles - March 11, 2024 Category: Chemistry Authors: Pragyan J. Hazarika Source Type: research

Consequences of twisting of the flexible arms of imidazole-derived urea in zinc-dicarboxylate coordination polymers
CrystEngComm, 2024, Advance Article DOI: 10.1039/D4CE00005F, PaperSatyendra Verma, Rinki Brahma, Jubaraj B. Baruah A semi-flexible imidazole-based urea ligand, 1-(3-(1H-imidazol-1-yl)propyl)-3-phenylurea, and three zinc-dicarboxylate coordination polymers possessing the ligand were synthesized and characterized. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - CrystEngComm latest articles)
Source: RSC - CrystEngComm latest articles - March 11, 2024 Category: Chemistry Authors: Satyendra Verma Source Type: research

Enantioselective enrichment of chiral 1-phenylethanol in the camphor-based chiral metal –organic framework CFA-22
CrystEngComm, 2024, Advance Article DOI: 10.1039/D4CE00181H, CommunicationRichard R öβ-Ohlenroth, Katharina Knippen, Maryana Kraft, Dirk Volkmer The novel enantioselectiveCFA-22 metal –organic frameworks were successfully developed and investigated for chiral adsorption separation ofe.g. racemic 1-phenylethanol. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - CrystEngComm latest articles)
Source: RSC - CrystEngComm latest articles - March 11, 2024 Category: Chemistry Authors: Richard R öβ-Ohlenroth Source Type: research

Synthesis and photophysical properties of charge transfer cocrystals based on TCNB and fluorene and its derivatives
CrystEngComm, 2024, Accepted Manuscript DOI: 10.1039/D3CE01208E, PaperWenxiu Yao, Pengfei Wu, Yidan Xie, Xinyu Shen, Shuwei Xia, Liangmin Yu A series of charge transfer cocrystals with fluorescent properties involving 1,2,4,5-tetracyanobenzene (TCNB, C10H2N4) as the acceptor, fluorene (FR, C13H10) and its bromide 2-bromofluorene (2-BrFR, C13H9Br), carbazole (CZ, C12H9N) and its... The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - CrystEngComm latest articles)
Source: RSC - CrystEngComm latest articles - March 11, 2024 Category: Chemistry Authors: Wenxiu Yao Source Type: research

Color-Resolved Mechanoluminescence of Eu and Mn Co-doped SrMg2(PO4)2
CrystEngComm, 2024, Accepted Manuscript DOI: 10.1039/D4CE00070F, PaperQingshan He, Yajing Yan, Ting Wang, Longchao Guo, Yang Yue, Nannan Zhu, Weifang Bu, Xin An, Bosong Duan, Xuanyu Zhu, Xue Yu Mechanoluminescence (ML) materials can convert mechanical stimuli into visible signals for real-time visualization of stress sensing. Since stress sensing solely based on ML absolute strength is susceptible to the external... The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - CrystEngComm latest articles)
Source: RSC - CrystEngComm latest articles - March 11, 2024 Category: Chemistry Authors: Qingshan He Source Type: research

Polyoxometalate templated silver-bisphosphine sandwich: structurally tunable hybrid materials
CrystEngComm, 2024, Advance Article DOI: 10.1039/D4CE00106K, PaperSheng-Jie Yao, Zhen-Qing Qi, Zhan-Guo Jiang, Cai-Hong Zhan This work describes complex macrocycle-POM hybrids with significant assembly patterns, interaction forces and exposed POM sites. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - CrystEngComm latest articles)
Source: RSC - CrystEngComm latest articles - March 8, 2024 Category: Chemistry Authors: Sheng-Jie Yao Source Type: research

A low-temperature self-flux route to prepare hexagonal rare earth fluorides and manipulation of upconversion luminescence in rodlike NaYbF4:Tm3+/Fe3+ crystals
CrystEngComm, 2024, Advance Article DOI: 10.1039/D3CE01159C, PaperXinyang Huang, Min Liao The distorted lattice, ET between Tm3+ and Fe3+ and no ET between Yb3+ and Fe3+ make 89Yb1Tm10Fe crystals obtained in low-temperature self-flux system exhibit the strongest emission with its absolute UCQY of 0.46% and of 0.56% with and without the magnetic field of 15 kOe, respectively. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - CrystEngComm latest articles)
Source: RSC - CrystEngComm latest articles - March 8, 2024 Category: Chemistry Authors: Xinyang Huang Source Type: research

Union is strength: π–π stacking interactions are capable of preventing solid-state racemization of tris-chelate complexes
CrystEngComm, 2024, Advance Article DOI: 10.1039/D4CE00104D, CommunicationAndrey V. Gavrikov, Andrey B. Ilyukhin The first reliable observation of the solid-phase racemization of the entire tris-chelate complex is reported. The decisive effect of the π–π stacking on this process is revealed. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry (Source: RSC - CrystEngComm latest articles)
Source: RSC - CrystEngComm latest articles - March 8, 2024 Category: Chemistry Authors: Andrey V. Gavrikov Source Type: research