Union is strength: π–π stacking interactions are capable of preventing solid-state racemization of tris-chelate complexes

CrystEngComm, 2024, Advance Article DOI: 10.1039/D4CE00104D, CommunicationAndrey V. Gavrikov, Andrey B. Ilyukhin The first reliable observation of the solid-phase racemization of the entire tris-chelate complex is reported. The decisive effect of the π–π stacking on this process is revealed. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry

Source: RSC - CrystEngComm latest articles - March 8, 2024 Category: Chemistry Authors: Andrey V. Gavrikov Source Type: research