Sulfonyl radical triggered selective iodosulfonylation and bicyclization of 1,6-dienes

Chem Commun (Camb). 2021 Jul 27. doi: 10.1039/d1cc03252f. Online ahead of print.ABSTRACTA novel sulfonyl radical triggered selective iodosulfonylation and bicyclization of 1,6-dienes has been described for the first time. High selectivity and efficiency, mild reaction conditions, excellent functional group compatibility, and broad substrate scope are the attractive features of this synthetic protocol, which provides a unique platform for precise radical cyclization.PMID:34318821 | DOI:10.1039/d1cc03252f

Source: Chemical Communications - July 28, 2021 Category: Chemistry Authors: Shi-Ping Wu Dong-Kai Wang Qing-Qing Kang Guo-Ping Ge Hongxing Zheng Meiling Zhu Ting Li Jun-Qi Zhang Wen-Ting Wei Source Type: research