Computational prediction of Au(I) –Pb(II) bonding in coordination complexes and study of the factors affecting the formation of Au(I)–E(II) (E = Ge, Sn, Pb) covalent bonds

Phys. Chem. Chem. Phys., 2021, Advance Article DOI: 10.1039/D1CP00325A, PaperJos é M. López-de-Luzuriaga, Miguel Monge, M. Elena Olmos, María Rodríguez-Castillo, Alba Sorroche Computational studies on Au(I) –E(II) in [R3PAu –(ECl3)] (E = Ge, Sn, Pb) model systems indicate the covalent dative nature from the [ECl3]− metalloligands to Au(I) fragments and predict the existence of Au(I) –Pb(II) bonds using electron widthdrawing PR3 ligands. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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