Characterizing Polyoxovanadate-alkoxide Clusters Using Vanadium K-edge X-ray Absorption Spectroscopy.

Characterizing Polyoxovanadate-alkoxide Clusters Using Vanadium K-edge X-ray Absorption Spectroscopy.
Chemistry. 2020 Oct 16;:
Authors: Kozimor SA, Meyer RL, Greer SM, Blake AV, Cary SK, Ditter AS, Daly SR, Li F, Matson EM, Mocko V, Seidler GT, Stein BW, Weinstein SD
Abstract
A number of technologies would benefit from developing inorganic compounds and materials with specific electronic and magnetic exchange properties. Unfortunately, designing compounds with these properties is difficult because metal···metal coupling schemes are hard to predict and control. Fully characterizing communication between metals in existing compounds that exhibit interesting properties could provide valuable insight and advance those predictive capabilities. One such class of molecules are the series of Lindqvist iron-functionalized and hexavanadium polyoxovanadate-alkoxide clusters, which we characterized here using V K-edge X-ray absorption spectroscopy. Substantial changes in the pre-edge peak intensities were observed that tracked with the V 3d-electron count. The data also suggested substantial delocalization between the vanadium cations. Meanwhile, the FeIII cations were electronically isolated from the polyoxovanadate core.
PMID: 33064328 [PubMed - as supplied by publisher]

Source: Chemistry - October 16, 2020 Category: Chemistry Authors: Kozimor SA, Meyer RL, Greer SM, Blake AV, Cary SK, Ditter AS, Daly SR, Li F, Matson EM, Mocko V, Seidler GT, Stein BW, Weinstein SD Tags: Chemistry Source Type: research