Virus ‐Templated Nickel Phosphide Nanofoams as Additive‐Free, Thin‐Film Li‐Ion Microbattery Anodes

Transition metal phosphides (TMP) are promising lithium ‐ion electrode materials. However, TMP syntheses remain underdeveloped regarding simultaneous control over phase composition and nanostructure. Here, M13 bacteriophage is employed to develop 3D nickel phosphide nanofoams with controllable phase composition and structural elements. Virus‐template d nanofoams are integrated as additive‐free, thin‐film, lithium‐ion microbattery electrodes. Virus‐templating can further enable TMP development in energy storage. AbstractTransition metal phosphides are a new class of materials generating interest as alternative negative electrodes in lithium ‐ion batteries. However, metal phosphide syntheses remain underdeveloped in terms of simultaneous control over phase composition and 3D nanostructure. Herein, M13 bacteriophage is employed as a biological scaffold to develop 3D nickel phosphide nanofoams with control over a range of phase composit ions and structural elements. Virus‐templated Ni5P4 nanofoams are then integrated as thin ‐film negative electrodes in lithium‐ion microbatteries, demonstrating a discharge capacity of 677 mAh g–1 (677 mAh cm–3) and an 80% capacity retention over more than 100 cycles. This strong electrochemical performance is attributed to the virus ‐templated, nanostructured morphology, which remains electronically conductive throughout cycling, thereby sidestepping the need for conductive additives. When accounting for the mass of addi...
Source: Small - Category: Nanotechnology Authors: Tags: Full Paper Source Type: research