A kinetic resolution strategy for the synthesis of chiral octahedral NHC-iridium(III) catalysts

Chem. Commun., 2019, Accepted Manuscript DOI: 10.1039/C9CC02434D, CommunicationOlivier Basle, Marc Mauduit, Jeanne Crassous, Ludovic Favereau, Karinne Miqueu, C crevisy, Vincent Dorcet, Thierry Roisnel, Thomas Viv ès, Robert Tarrieu, Delphine Pichon, Romane Manguin The transmetalation reaction of a chiral-bidentate NHC-silver complex to racemic [Ir(Cl)(ppy)2]2 operates with kinetic resolution leading to chiral octahedral NHC-iridium(III) complexes and enantio-enriched bis-cyclometalated iridium(III) complexes. The iridium(III) complexes demonstrated... The content of this RSS Feed (c) The Royal Society of Chemistry

Source: RSC - Chem. Commun. latest articles - April 25, 2019 Category: Chemistry Authors: Olivier Basle Source Type: research