Gold nanoparticle/reduced graphene oxide hybrids for fast light-actuated shape memory polymers with enhanced photothermal conversion and mechanical stiffness

Publication date: Available online 15 April 2019Source: European Polymer JournalAuthor(s): Song-tai Li, Xin-zheng Jin, Yao-wen Shao, Xiao-dong Qi, Jing-hui Yang, Yong WangAbstractA fast light-actuated shape memory polymer (SMP) composite with greatly enhanced photothermal conversion and mechanical stiffness was prepared by incorporating gold nanoparticle/reduced graphene oxide (AuNP-RGO) hybrids into cross-linked poly(ε-caprolactone) (PCL). The AuNP-RGO hybrids with AuNPs uniformly anchored on RGO sheets were obtained in a water/n-butylamine system. Due to the homogeneous dispersion of AuNP-RGO in PCL matrix and the synergistic effect of photothermal conversion, the AuNP-RGO hybrids imparted the PCL with fast near-infrared (NIR) light-actuated shape recovery effect, and the light-actuated shape recovery speed could be accelerated via the increase of AuNP loading on RGO sheets. Moreover, the SMP composites possessed high shape recovery stress due to the incorporation of AuNP-RGO, thus they could be used as heavy-lift actuators. This SMP composites with enhanced light responsivity and mechanical properties are believed to have great potential in many fields such as light energy harvesting and remote-controlled actuators.Graphical abstractA fast light-actuated shape memory polymer (SMP) composite with synergistically enhanced photothermal conversion and mechanical stiffness was prepared by incorporating gold nanoparticle/reduced graphene oxide (AuNP-RGO) hybrids into poly(ε-ca...
Source: European Polymer Journal - Category: Chemistry Source Type: research