Organosoluble tetravalent actinide di- and trifluorides.

Organosoluble tetravalent actinide di- and trifluorides.
Chem Commun (Camb). 2018 Oct 10;:
Authors: Gotthelf G, Stuber MA, Kornienko AY, Emge TJ, Brennan JG
Abstract
Soluble molecular actinide(iv) fluorides can be prepared in high yield via redox or metathesis reactions of silver fluorides with actinide compounds containing ancillary iodide or fluorinated thiolate ligands. Two compounds, (py)4UF2I2·2py and (py)7Th2F5(SC6F5)3·2py were isolated and characterized by conventional methods, powder and low temperature single crystal X-ray diffraction.
PMID: 30302458 [PubMed - as supplied by publisher]

Source: Chemical Communications - October 10, 2018 Category: Chemistry Authors: Gotthelf G, Stuber MA, Kornienko AY, Emge TJ, Brennan JG Tags: Chem Commun (Camb) Source Type: research