A missing member of conjugated N-heterocycles: Realizing pyrido[1,2-[small alpha]]azepine by reacting ruthenium alkenylcarbene complex with alkyne

Chem. Commun., 2018, Accepted Manuscript DOI: 10.1039/C8CC00758F, CommunicationXiaoxi Zhou, Fanping Huang, Chun Tang, Qingde Zhuo, Zhixin Chen, Hong Zhang, Haiping Xia Despite the rich chemistry of N-heterocycles, pyrido[1,2-[small alpha]]azepine remains elusive due to its potential antiaromaticity and lability. Here, we demonstrate the synthesis and characterization of the first bicyclic pyrido[1,2-[small alpha]]azepine that leverages... The content of this RSS Feed (c) The Royal Society of Chemistry

Source: RSC - Chem. Commun. latest articles - March 21, 2018 Category: Chemistry Authors: Xiaoxi Zhou Source Type: research