Cyanotrifluoromethylthiolation of unactivated dialkyl-substituted alkynes via cyano migration: synthesis of trifluoromethylthiolated acrylonitrile

Chem. Commun., 2018, Accepted Manuscript DOI: 10.1039/C8CC01189C, CommunicationMeishan Ji, Jiajia Yu, Chen Zhu Reported herein is a novel, elusive cyanotrifluoromethylthiolation of unactivated dialkyl-substituted alkynes. Taken advantage of the strategy of intramolecular cyano migration, the reaction proceeds stereoselectively to deliver the E-olefinic products. A... The content of this RSS Feed (c) The Royal Society of Chemistry

Source: RSC - Chem. Commun. latest articles - March 21, 2018 Category: Chemistry Authors: Meishan Ji Source Type: research