Highly enhanced electromechanical properties of PVDF-TrFE/SWCNT nanocomposites using an efficient polymer compatibilizer

Publication date: 22 March 2018 Source:Composites Science and Technology, Volume 157 Author(s): Kie Yong Cho, Hyunchul Park, Hyun-Ji Kim, Xuan Huy Do, Chong Min Koo, Seung Sang Hwang, Ho Gyu Yoon, Kyung-Youl Baek PVDF-TrFE/SWCNT nanocomposites with outstanding electromechanical properties were produced using P3HT-PMMA block copolymers as a compatibilizer between PVDF-TrFE and SWCNT. P3HT-PMMA block copolymer coated SWCNT (PTMCNT) was first prepared to utilize π-π stacking interactions between SWCNT and the P3HT block segment. The obtained PTMCNTs are highly compatible with the PVDF-TrFE matrix due to strong hydrogen bonding interaction between the polymer matrix and the PMMA block segment on the surface of SWCNT, leading to a very low percolation behavior at 0.05 wt% of SWCNT in PVDF-TrFE. The obtained electroactive PVDF-TrFE/SWCNT nanocomposites showed ca. 50 times increased electromechanical thickness strain, ca. 3200 times increased elastic energy density, and ca. 460 times increased electrical-to-mechanical energy conversion rate in comparison to those of pristine PVDF-TrFE at the relatively low electric field (50 Vppμm-1). These outstanding properties result from the ultra-low percolation of SWCNT along with uniform local field distribution in PVDF-TrFE, which kept not only intrinsic properties of PVDF-TrFE such as all-trans formed crystalline phase and softness but also enhanced electrical properties including dielectric constant. Graphical abstract

Source: Composites Science and Technology - February 3, 2018 Category: Science Source Type: research