Mechanistic Insight into the Electronic Influences Imposed by Substituent Variation in Polyazine-Bridged Ruthenium(II)/Rhodium(III) Supramolecules.

Mechanistic Insight into the Electronic Influences Imposed by Substituent Variation in Polyazine-Bridged Ruthenium(II)/Rhodium(III) Supramolecules.
Chemistry. 2014 Jun 4;
Authors: White TA, Mallalieu HE, Wang J, Brewer KJ
Abstract
Invited for the cover of this issue are researchers from the Department of Chemistry at Virginia Tech featuring work on electrochemical properties of photochemical molecular devices for solar hydrogen production. The image highlights the complexity of the redox chemistry of the studied supramolecules, detailing speciation following reduction. Mr. Skye King assisted in the development of the molecular models for the cover. Read the full text of the article at 10.1002/chem.201402564.
PMID: 24898974 [PubMed - as supplied by publisher]

Source: Chemistry - June 4, 2014 Category: Chemistry Authors: White TA, Mallalieu HE, Wang J, Brewer KJ Tags: Chemistry Source Type: research