Conductive MXene/Polymer Composites for Transparent Flexible Supercapacitors

The synergistically interacting Ti3C2Tx/PEDOT:PSS composite is reported for all-solid-state transparent flexible symmetric supercapacitors with an outstanding areal capacitance of 3.1 mF  cm−2, a high optical transparency of 61.6%, and excellent flexibility and durability, which hold significant promise for wearable and portable energy storage applications. AbstractTransparent flexible energy storage devices are limited by the trade-off among flexibility, transparency, and charge storage capability of their electrode materials. Conductive polymers are intrinsically flexible, but limited by small capacitance. Pseudocapacitive MXene provides high capacitance, yet their opaque and brittle nature hinders their flexibility and transparency. Herein, the development of synergistically interacting conductive polymer Ti3C2Tx MXene/PEDOT:PSS composites is reported for transparent flexible all-solid-state supercapacitors, with an outstanding areal capacitance of 3.1 mF  cm−2, a high optical transparency of 61.6%, and excellent flexibility and durability. The high capacitance and high transparency of the devices stem from the uniform and thorough blending of PEDOT:PSS and Ti3C2Tx, which is associated with the formation of O ─H…O H-bonds in the composites. The conductive MXene/polymer composite electrodes demonstrate a rational means to achieve high-capacity, transparent and flexible supercapacitors in an easy and scalable manner.

Source: Small - May 3, 2024 Category: Nanotechnology Authors: Shan Ren, Xiangyu Pan, Yangyang Zhang, Jianlong Xu, Zhifang Liu, Xuanyi Zhang, Xian Li, Xu Gao, Yanan Zhong, Sheng Chen, Sui ‐Dong Wang Tags: Research Article Source Type: research