Comparative Microplastic Analysis in Urban Waters Using μ-FTIR And Py-GC-MS: A Case Study in Amsterdam

This study presents the first comparative results on urban water samples using micro Fourier-transform infrared (μ-FTIR) imaging and pyrolysis-gas chromatography-mass spectrometry (Py-GC-MS) to identify and quantify MPs in both particle numbers and mass concentration. Two sampling campaigns in summer and winter were conducted at 11 locations within the Amsterdam canal network. An advanced in-situ volume-reducing sampling pump was employed to collect MPs from the surface water within the size fraction of 10-300 μm. The analysis revealed MP concentrations within the range of 16 -107 MP/m3, estimated to be 2.0-789 μg/m3 by μ-FTIR imaging and 8.5-754 μg/m3 by Py-GC-MS. The results of the two analysis techniques showed good comparability in terms of the general trends of MP abundances, with variations in polymer compositions due to the inherent inter-methodological differences. Elevated MP concentrations were observed in the city center compared to the suburban areas. In addition, seasonal differences in MP abundances were noted at the locations with high human activity.PMID:38697250 | DOI:10.1016/j.envpol.2024.124088
Source: Environmental Pollution - Category: Environmental Health Authors: Source Type: research