Intercalating a potassium-aqua complex cation into an α-MoO < sub > 3 < /sub > layer without reducing molybdenum: a potential storage system

Chem Commun (Camb). 2024 Apr 30. doi: 10.1039/d4cc01400f. Online ahead of print.ABSTRACTWe have demonstrated a green aqueous synthesis of rod-shaped MoO3 material, [MoVI3O9{K(H2O)4}(CH3COO)]·H2O (2) intercalating potassium-aqua-complex acetate into its lamellar space, simply by ion-exchange of Co(II)-aqua-complex in compound [MoVI4O12(CH3COO)2{CoII(H2O)6}]·2H2O (1) by {K(H2O)4}+ in an aqueous solution of 1 and KCl. Compound 2 acts as a potential storage system of alkali metal ions.PMID:38686497 | DOI:10.1039/d4cc01400f
Source: Chemical Communications - Category: Chemistry Authors: Source Type: research