Visible light-promoted [3+2] cyclization reaction of vinyl azides with perfluoroalkyl-substituted-imidoyl sulfoxonium ylides

Chem Commun (Camb). 2024 Apr 29. doi: 10.1039/d4cc00777h. Online ahead of print.ABSTRACTVisible-light-induced [3+2] cyclization of vinyl azides with perfluoroalkyl-substituted imidoyl sulfoxonium ylides has been developed for the first time. In this transformation, perfluoroalkyl-substituted imidoyl sulfoxonium ylides are firstly employed as a carbon radical precursor under visible light irradiation, providing a new and efficient method for the construction of perfluoroalkyl-substituted 1-pyrrolines.PMID:38683050 | DOI:10.1039/d4cc00777h

Source: Chemical Communications - April 29, 2024 Category: Chemistry Authors: Ming Yang Yu-Xuan Meng Haroon Mehfooz Yu-Long Zhao Source Type: research