Synthesis of the A/D/E-ring Core Compounds of Maoecrystal V

Biosci Biotechnol Biochem. 2024 Apr 23:zbae049. doi: 10.1093/bbb/zbae049. Online ahead of print.ABSTRACTSynthesis of the A/D/E-ring core compounds of maoecrystal V was achieved. The key Diels-Alder reactions between tricyclic α-methylene lactones and Kitahara-Danishefsky dienes afforded the spirocyclic core compounds in a regioselective and stereoselective manner.PMID:38653727 | DOI:10.1093/bbb/zbae049

Source: Bioscience, Biotechnology, and Biochemistry - April 23, 2024 Category: Biochemistry Authors: Hiroki Asao Yasuharu Shimasaki Ayaka Sasaki Shunki Katayama Kousuke Ida Masaaki Kotake Eriko Sato Yuki Sato Taiki Ishimoto Minoru Izumi Christopher J Vavricka Kuwahara Shigefumi Hiromasa Kiyota Source Type: research