Solvent-free copper-catalyzed trisilylation of alkynes: a practical and atom-economical approach for accessing 1,1,1-trisilylalkanes

This article is licensed under aCreative Commons Attribution 3.0 Unported Licence.Jia Li, Shaozhong Ge Copper-catalyzed 1,1,1-trisilylation of alkynes was developed with Cu(OAc)2 and PnBu3. Mechanistic studies reveal that this reaction occurs through sequential dehydrogenative silylation of alkynes and dihydrosilylation of alkynylsilane intermediates. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry

Source: RSC - Green Chem. latest articles - April 19, 2024 Category: Chemistry Authors: Jia Li Source Type: research