Protic- or anionic-NHCs with a classical-NHC in a single [Ru(CNC)(PPh3)2Cl]Cl pincer complex: direct comparison of structure & electronic properties and heterolytic H2 splitting

Dalton Trans., 2024, Advance Article DOI: 10.1039/D4DT00623B, CommunicationNavdeep Srivastava, Amrendra K. Singh A set of pincer complexes1,2 and2 ’ having a protic- or anionic-NHC and a classical-NHC in the same molecule are reported. Cooperation between metal and ligand in2' is indicated by the heterolytic splitting of H2 to give the Ru-hydride complex3. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry

Source: RSC - Dalton Trans. latest articles - April 10, 2024 Category: Chemistry Authors: Navdeep Srivastava Source Type: research