Highly active and regioselective hydroaminomethylation of olefins catalyzed by Rh/sulfoxantphos with ZSM-5

Chem Commun (Camb). 2024 Apr 9. doi: 10.1039/d4cc00663a. Online ahead of print.ABSTRACTRh-catalyzed hydroaminomethylation has been developed with acid sulfoxantphos and ZSM-5. Linear amines were obtained in good yields (71-95%) with high l/b ratios (up to 132.4) and excellent TON values (up to 23 760). The ZSM-5 and SO3H group of ligands improved the performances of hydroformylation and reductive amination.PMID:38591607 | DOI:10.1039/d4cc00663a

Source: Chemical Communications - April 9, 2024 Category: Chemistry Authors: Xiaoshuang Yuan Xueqing Zhang Zhaohui Zheng Shuhui Sun Xiaofei Jia Shuxiang Dong Source Type: research