Dissipative sequential catalysis < em > via < /em > six-component machinery

Chem Commun (Camb). 2024 Apr 10. doi: 10.1039/d4cc00786g. Online ahead of print.ABSTRACTTriphenyl phosphane (TPP) and an epoxide as a fuel system transiently transformed a non-catalytic six-component turnstile into a four-component catalytic rotor releasing N-methyl pyrrolidine and a copper(I) complex. The two latter compounds acted synergistically as catalysts to perform first a Michael addition and then a 5-exo-dig cyclization, giving rise to dissipative sequential catalysis.PMID:38596877 | DOI:10.1039/d4cc00786g

Source: Chemical Communications - April 10, 2024 Category: Chemistry Authors: Debabrata Mondal Emad Elramadi Sohom Kundu Michael Schmittel Source Type: research