Exploring sulfur donor atom coordination chemistry with La(II), Nd(II), and Tm(II) using a terphenylthiolate ligand

Chem. Commun., 2024, Advance Article DOI: 10.1039/D4CC01037J, CommunicationKito Gilbert-Bass, Cary R. Stennett, Robin Grotjahn, Joseph W. Ziller, Filipp Furche, William J. Evans To expand the range of donor atoms known to stabilize 4fn5d1 Ln(II) ions beyond C, N, and O first row main group donor atoms, the Ln(III) terphenylthiolate iodides, LnIII(SAriPr6)2I (AriPr6 = C6H3-2,6-(C6H2-2,4,6-iPr3)2, Ln = La, Nd) were reduced to LnII(SAriPr6)2 complexes. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry

Source: RSC - Chem. Commun. latest articles - April 8, 2024 Category: Chemistry Authors: Kito Gilbert-Bass Source Type: research