Dioxane promoted photochemical < em > O < /em > -alkylation of 1,3-dicarbonyl compounds beyond carbene insertion into C-H and C-C bonds

Chem Commun (Camb). 2024 Mar 28. doi: 10.1039/d4cc00778f. Online ahead of print.ABSTRACTA photochemical synthesis of enol ethers and furan-3(2H)-ones from 1,3-dicarbonyl compounds and aryl diazoacetates has been developed. Significantly, 1,4-dioxane promoted O-alkylation of various 1,3-dicarbonyl compounds beyond previous carbene insertion into C-H and C-C bonds has been disclosed.PMID:38545739 | DOI:10.1039/d4cc00778f

Source: Chemical Communications - March 28, 2024 Category: Chemistry Authors: Xinlong Zhou Jingjing Jiang Min Zhang Qingqing Wu Keyong Zhu Dongjie Shi Sensen Hou Jingjing Zhao Pan Li Source Type: research