A dynamic covalent approach to [Pt < sub > < em > n < /em > < /sub > L < sub > 2 < em > n < /em > < /sub > ] < sup > 2 < em > n < /em > + < /sup > cages

Chem Commun (Camb). 2024 Mar 26. doi: 10.1039/d4cc00323c. Online ahead of print.ABSTRACTA dynamic covalent approach was exploited to generate a family of homometallic [PtnL2n]2n+ cage (predominantly [Pt2L4]4+ systems) architectures. The family of platinum(II) architectures were characterized using 1H nuclear magnetic resonance (NMR) and diffusion ordered spectroscopy (DOSY), electrospray ionization mass spectrometry (ESI-MS) and the molecular structures of two cages were determined by X-ray crystallography.PMID:38530770 | DOI:10.1039/d4cc00323c

Source: Chemical Communications - March 26, 2024 Category: Chemistry Authors: Quinn V C van Hilst Aston C Pearcy Dan Preston L James Wright Christian G Hartinger Heather J L Brooks James D Crowley Source Type: research