New Insights into the Mechanism and Kinetics of the Addition Reaction of Unsaturated Criegee Intermediates to CF3COOH and Tropospheric Implications

Environ. Sci.: Processes Impacts, 2024, Accepted Manuscript DOI: 10.1039/D3EM00554B, PaperMakroni Lily, Xiaofan Lv, Asit K. Chandra, Narcisse Tsona Tchinda, Lin Du In this work, we have investigated the mechanism, thermochemistry and kinetics of the reaction of syn-cis-CH2=RzCRyC=O+O- (where Rz, Ry=H, CH3-) unsaturated Criegee intermediates (Cls) with CF3COOH using quantum chemical methods.... The content of this RSS Feed (c) The Royal Society of Chemistry
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