Zeta potential of crude oil in aqueous solution

Adv Colloid Interface Sci. 2023 Jul 18;320:102962. doi: 10.1016/j.cis.2023.102962. Online ahead of print.ABSTRACTDespite the broad range of interest and applications, controls on the surface charge of crude oil in aqueous solution remain poorly understood. The primary data source to understand the surface charge on crude oil comprises measurements of zeta potential on individual drops or emulsions obtained using the electrophoretic method (EPM). Here we (i) collate and review previous measurements of zeta potential on crude oil, (ii) compare and contrast the results, and (iii) report new measurements of zeta potential on crude oil wetting films and layers relevant to oil-saturated porous media, obtained using the streaming potential method (SPM). Results show that the zeta potential depends on electrolyte pH and the concentration of divalent ions Ca2+ and Mg2+. Lower pH and higher concentration of these divalent ions yields more positive zeta potential. The isoelectric point (IEP) in simple NaCl electrolytes lies in the pH range 3-5. The IEP in simple CaCl2 and MgCl2 electrolytes can be expressed as pCa or pMg, respectively, and lies in the range 0-1. Close to the IEP, the zeta potential varies linearly with pH, pCa or pMg, suggesting simple Nernstian behaviour of the crude oil surface. The sensitivity of the zeta potential to pH, pCa and pMg decreases with increasing total ionic strength. The impact of pH, pCa and pMg on zeta potential varies significantly across different c...
Source: Advances in Colloid and Interface Science - Category: Chemistry Authors: Source Type: research