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Total 37 results found since Jan 2013.

Alkaline Ni-Zn Rechargeable Batteries for Sustainable Energy Storage: Battery Components, Deterioration Mechanisms, and Impact of Additives
ChemSusChem. 2023 Sep 8:e202300940. doi: 10.1002/cssc.202300940. Online ahead of print.ABSTRACTThe demand for long-term, sustainable, and low-cost battery energy storage systems with high power delivery capabilities for stationary grid-scale energy storage, as well as the necessity for safe lithium-ion battery alternatives, has renewed interest in aqueous zinc-based rechargeable batteries. The Alkaline Ni-Zn rechargeable battery chemistry was identified as a promising technology for sustainable energy storage applications, albeit a considerable investment in academic research, it still fails to deliver the requisite perfor...
Source: ChemSusChem - September 8, 2023 Category: Chemistry Authors: Katerina Bogomolov Yair Ein-Eli Source Type: research

Exploring the Impact of Lithium Halide-based Redox Mediators in Suppressing CO2 Evolution in Li-O2 Cells
This article is licensed under aCreative Commons Attribution 3.0 Unported Licence.Sri Harsha Akella, Bagavathi Muniyandi, Rosy ., Daniel Sharon, Ömer Özgür Çapraz, Malachi Noked The realization of lithium-oxygen (Li-O2) batteries has been impeded by parasitic reactions that cause cell component degradation, often accompanied by the release of CO2 gas during oxidation reactions. The use... The content of this RSS Feed (c) The Royal Society of Chemistry
Source: RSC - J. Mater. Chem. latest articles - August 16, 2023 Category: Chemistry Authors: Sri Harsha Akella Source Type: research

Balancing Interfacial Reactions through Regulating p-Band Centers by an Indium Tin Oxide Protective Layer for Stable Zn Metal Anodes
Angew Chem Int Ed Engl. 2023 Aug 10:e202308454. doi: 10.1002/anie.202308454. Online ahead of print.ABSTRACTMetallic zinc (Zn) is considered as one of the most attractive anode materials for the post-lithium metal battery systems owing to the high theoretical capacity, low cost, and intrinsic safety. However, the Zn dendrites and parasitic side reaction impede its application. Herein, we propose a new principle of regulating p-band center of metal oxide protective coating to balance Zn adsorption energy and migration energy barrier for effective Zn deposition and stripping. Experimental results and theoretical calculations ...
Source: Angewandte Chemie - August 10, 2023 Category: Chemistry Authors: Yahan Meng Mingming Wang Jingwen Xu Kui Xu Kai Zhang Zehui Xie Zhengxin Zhu Weiping Wang Pengfei Gao Xiangyang Li Wei Chen Source Type: research

Surface Modification on Nickel rich Cathode Materials for Lithium-Ion Cells: A Mini Review
Chem Rec. 2023 Jul 3:e202300132. doi: 10.1002/tcr.202300132. Online ahead of print.ABSTRACTNickel-rich (Ni-rich) layered oxides are considered as the most promising cathode candidates for lithium-ion cells owing to their high theoretical specific capacity. However, the higher nickel content endows structural deformation through unwanted phase transitions and parasitic side reactions that lead to capacity fading upon prolonged cycling. Hence, a deep understanding of the chemistry and structural behaviour is essential for developing Ni-rich Lithium Nickel Cobalt Manganese oxide (NCM) cathode-based high-energy batteries. The ...
Source: Chemical Record - July 3, 2023 Category: Chemistry Authors: M Akhilash P S Salini Bibin John S Sujatha T D Mercy Source Type: research

Catalytic Chemistry Derived Artificial Solid Electrolyte Interphase for Stable Lithium Metal Anodes Working at 20 mA cm-2 and 20 mAh cm-2
Angew Chem Int Ed Engl. 2023 Jun 7:e202305723. doi: 10.1002/anie.202305723. Online ahead of print.ABSTRACTA stable solid electrolyte interphase (SEI) layer is crucial for lithium metal anode (LMA) to survive in long-term cycling. However, chaotic structures and chemical inhomogeneity of natural SEI make LMA suffer from exasperating dendrite growth and severe electrode pulverization, hindering the practical application of LMAs. Here, we design a catalyst-derived artificial SEI layer with an ordered polyamide (PA)-LiOH (PA-LiOH) bi-phase structure to modulate ion transport and enable dendrite-free Li deposition. The PA-LiOH ...
Source: Angewandte Chemie - June 7, 2023 Category: Chemistry Authors: Yifeng Cheng Zhijie Wang Jinbiao Chen Yuanmao Chen Xi Ke Duojie Wu Qing Zhang Yuanmin Zhu Xuming Yang Meng Gu Zaiping Guo Zhicong Shi Source Type: research

An Organodiselenide Comediator to Facilitate Sulfur Redox Kinetics in Lithium-Sulfur Batteries with Encapsulating Lithium Polysulfide Electrolyte
Angew Chem Int Ed Engl. 2023 May 30:e202303363. doi: 10.1002/anie.202303363. Online ahead of print.ABSTRACTLithium-sulfur (Li-S) batteries are regarded as promising high-energy-density energy storage devices. However, the cycling stability of Li-S batteries is restricted by the parasitic reactions between Li metal anodes and soluble lithium polysulfides (LiPSs). Encapsulating LiPS electrolyte (EPSE) can efficiently suppress the parasitic reactions but inevitably sacrifices the cathode sulfur redox kinetics. To address the above dilemma, a redox comediation strategy for EPSE is proposed to realize high-energy-density and lo...
Source: Angewandte Chemie - May 30, 2023 Category: Chemistry Authors: Yiran Liu Meng Zhao Li-Peng Hou Zheng Li Chen-Xi Bi Zi-Xian Chen Qian Cheng Xue-Qiang Zhang Bo-Quan Li Stefan Kaskel Jia-Qi Huang Source Type: research

DETECTING AND SUPPRESSING SPURIOUS SINGLET OXYGEN IN OPERANDO Li-O2 BATTERIES
Faraday Discuss., 2023, Accepted Manuscript DOI: 10.1039/D3FD00081H, PaperDaniel Cordoba, Leandro Benavidez, Daniel Horacio Murgida, Hernan Bernardo Rodriguez, Ernesto Julio Calvo The rechargeable lithium air (oxygen) battery (Li-O2) has very high energy density comparable to fossil fuels ( ∽3,600 Wh/kg). However, the parasitic reactions of the O2- reduction products with solvent and... The content of this RSS Feed (c) The Royal Society of Chemistry
Source: RSC - Faraday Discuss. latest articles - May 12, 2023 Category: Chemistry Authors: Daniel Cordoba Source Type: research

Electron Redistribution Enables Redox-Resistible Li6PS5Cl towards High-Performance All-Solid-State Lithium Batteries
This study highlights the electronic structure modulation to address redox issues on sulfide-based lithium batteries.PMID:36988084 | DOI:10.1002/anie.202302655
Source: Angewandte Chemie - March 29, 2023 Category: Chemistry Authors: Chong Liu Butian Chen Tianran Zhang Jicheng Zhang Ruoyu Wang Jian Zheng Qianjiang Mao Xiangfeng Liu Source Type: research

Mitigating Swelling of the Solid Electrolyte Interphase using an Inorganic Anion Switch for Low-temperature Lithium-ion Batteries
Angew Chem Int Ed Engl. 2023 Feb 25:e202300384. doi: 10.1002/anie.202300384. Online ahead of print.ABSTRACTIn overcoming the Li+ desolvation barrier for low-temperature battery operation, a weakly-solvated electrolyte based on carboxylate solvent has shown promises. In case of an organic-anion-enriched primary solvation sheath (PSS), we found that the electrolyte tends to form a highly swollen, unstable solid electrolyte interphase (SEI) that shows a high permeability to the electrolyte components, accounting for quickly declined electrochemical performance of graphite-based anode. Here we proposed a facile strategy to tun...
Source: Angewandte Chemie - February 25, 2023 Category: Chemistry Authors: Jia-Yan Liang Yanyan Zhang Sen Xin Shuang-Jie Tan Xin-Hai Meng Wen-Peng Wang Ji-Lei Shi Zhen-Bo Wang Fuyi Wang Li-Jun Wan Yu-Guo Guo Source Type: research

Rational Design of Covalent Organic Frameworks as Gas Diffusion Layers for Multi-atmosphere Lithium-Air Batteries
Angew Chem Int Ed Engl. 2023 Jan 10. doi: 10.1002/anie.202217869. Online ahead of print.ABSTRACTNon-aqueous Li-air batteries, despite their high energy density and low cost, have not been deployed practically due to their instability in ambient air, where moisture causes parasitic reactions and shortens their life drastically. Here, we demonstrate the rational design of nanoporous covalent organic frameworks (COFs) as effective gas diffusion layers (GDLs) to address this constraint. The COF GDLs, with a tailor-made pore size of ~1.4 nm and superhydrophobicity can limit the intrusion of organic electrolytes and moisture int...
Source: Angewandte Chemie - January 10, 2023 Category: Chemistry Authors: Xing Li Kun Zhang Zhen Li Youguo Yan Yijia Yuan Li Ma Keyu Xie Kian Ping Loh Source Type: research

An “Immobilizing and Relocating” Strategy for Highly Reversible Metallic Zinc Anode
J. Mater. Chem. A, 2023, Accepted Manuscript DOI: 10.1039/D2TA08498H, PaperRui Yao, Long Qian, Guangyao Zhao, Haojie Zhu, Tingting Qin, Chengxiang Xiao, Hai Lin, Feiyu Kang, Chunyi Zhi, Cheng Yang Over the last decade, aqueous metallic zinc batteries have aroused broad attention as a complementary alternative to lithium-ion batteries due to their safe and eco-friendly characteristics. However, the parasitic reactions... The content of this RSS Feed (c) The Royal Society of Chemistry
Source: RSC - J. Mater. Chem. latest articles - December 14, 2022 Category: Chemistry Authors: Rui Yao Source Type: research