Green solid-phase microextraction fiber coating based on the metal-organic framework CIM-80(Al): Analytical performance evaluation in direct immersion and headspace using gas chromatography and mass spectrometry for the analysis of water, urine and brewed coffee.

Green solid-phase microextraction fiber coating based on the metal-organic framework CIM-80(Al): Analytical performance evaluation in direct immersion and headspace using gas chromatography and mass spectrometry for the analysis of water, urine and brewed coffee.
Anal Chim Acta. 2020 Oct 09;1133:137-149
Authors: Pacheco-Fernández I, Rentero M, Ayala JH, Pasán J, Pino V
Abstract
A new solid-phase microextraction (SPME) fiber coating was prepared by the immobilization of the metal-organic framework (MOF) CIM-80(Al) on nitinol wires by a green in situ growth approach, using an aqueous synthetic approach, and without the need of any additional material to ensure the attachment of the MOF to the nitinol support. The coating was used for the development of headspace (HS) and direct immersion (DI) SPME methods in combination with gas chromatography and mass spectrometry (GC-MS) for the determination of polycyclic aromatic hydrocarbons (PAHs) as model compounds. Both methods were optimized and validated using the MOF-based fiber together with the commercial polydimethylsiloxane (PDMS) fiber. The MOF extraction phase exhibited superior analytical performance for most of the PAHs in HS-SPME mode (and particularly for less volatiles), while the PDMS fiber presented better results in the DI-SPME method. The analytical performance of the MOF sorbent coating in HS- and DI-SPME methods was also evaluated in urine and brewed coffee samples, withou...

Source: Analytica Chimica Acta - October 1, 2020 Category: Chemistry Authors: Pacheco-Fernández I, Rentero M, Ayala JH, Pasán J, Pino V Tags: Anal Chim Acta Source Type: research