Dual visible/NIR emission from organometallic iridium(III) complexes

Publication date: Available online 25 April 2019Source: Journal of Organometallic ChemistryAuthor(s): Kaitlin A. Phillips, Thomas M. Stonelake, Peter N. Horton, Simon J. Coles, Andrew J. Hallett, Sean P. O'Kell, Joseph M. Beames, Simon J.A. PopeAbstractA series of four substituted benzo[g]quinoxaline species have been synthesised and utilised as cyclometalating ligands for iridium(III). The ligands (L1-L4) were synthesised and isolated in good yield following the condensation of 2,3-diaminonaphthalene with benzil and three of its derivatives. The substituent modulated electronic properties of L1-L4 were dominated by intraligand π−π* transitions, with the fluorescence profile demonstrating vibronic features attributed to the highly conjugated nature of the chromophore. Iridium(III) complexes of the form [Ir(L)2(bipy)]PF6 were synthesised from L1-L4 in two steps. The electronic properties of the complexes reveal absorption in the UV-vis. Region with spin forbidden metal-to-ligand charge transfer (MLCT) transitions possibly contributing at longer wavelengths to ca. 600 nm. Steady state luminescence (aerated, room temperature) on solutions of the complexes showed dual emissive properties in the visible and near-infra red (NIR) regions. Firstly, a vibronically structured emission in the visible region (centred ca. 525 nm) was attributed to ligand centred fluorescence. Secondly, a broad emission peak in the NIR (ca. 950 nm) which extended to around 1200 nm was observed ...

Source: Journal of Organometallic Chemistry - April 25, 2019 Category: Chemistry Source Type: research