High-Spin Enforcement in First-Row Metal Complexes of a Constrained Polyaromatic Ligand: Synthesis, Structure, and Properties

New J. Chem., 2018, Accepted Manuscript DOI: 10.1039/C8NJ02072H, PaperLizhu Chen, Hunter A Dulaney, Branford O Wilkins, Sarah Farmer, Yanbing Zhang, Frank R Fronczek, Jonah W. Jurss The coordination chemistry of a rigid tetradentate polypyridyl ligand has been developed with first-row transition metals Mn(II), Fe(II), Co(II), Ni(II), and Zn(II). The polyaromatic ligand, 2,2 ’-di([2,2’-bipyridin]-6-yl)-1,1’-biphenyl (5, bpbb), is comprised... The content of this RSS Feed (c) The Royal Society of Chemistry

Source: RSC - New J. Chem. latest articles - October 19, 2018 Category: Chemistry Authors: Lizhu Chen Source Type: research