Observation of Nd ordering in a novel double perovskite Nd2MgRuO6 with weak exchange interaction at B-site

Publication date: March 2018 Source:Journal of Solid State Chemistry, Volume 259 Author(s): M.P. Sharannia, Paula Kayser, S. Savitha Pillai, Brendan J. Kennedy, Maxim Avdeev, R. Nirmala, P.N. Santhosh Polycrystalline Nd2MgRuO6 has monoclinic P2 1 /n structure with an ordered arrangement of Mg2+ and Ru4+ ions. Magnetic ordering is observed at 1.5K where the Ru sublattice exhibits type-I antiferromagnetic order with the magnetic moments parallel to the c-axis. The Nd3+ cations show a ferromagnetic arrangement at this temperature. Nd2MgRuO6 exhibits semiconductor like behaviour. Impedance analysis shows the contribution of grain alone to the conduction process till 231K, above which both the grain and grain boundary contribute. Graphical abstract

Source: Journal of Solid State Chemistry - February 3, 2018 Category: Chemistry Source Type: research