Palladium ‐Catalyzed [3 3] Annulation of Vinyl Chromium(0) Carbene Complexes through Carbene Migratory Insertion/Tsuji–Trost Reaction

AngewchemPalladium ‐Catalyzed [3 3] Annulation of Vinyl Chromium(0) Carbene Complexes through Carbene Migratory Insertion/Tsuji–Trost Reaction: Vinyl chromium(0) Fischer carbene complexes were employed as the source of π‐allylic palladium species for catalytic [3+3] annulation under palladium catalysis. Mechanistically, this transformation is...

Source: Organometallic Current - September 13, 2017 Category: Chemistry Tags: annulation Pd Catalyzed Source Type: blogs