A Radical Smiles Rearrangement Difunctionalization of Activated Alkenes via Desulfonylation and Insertion of Sulfur Dioxide Relay Strategy

Green Chem., 2024, Accepted Manuscript DOI: 10.1039/D4GC00186A, PaperSi-Wei Tian, Zhen-Tao Luo, Biquan Xiong, Kewen Tang, Pengfei Huang, Yu Liu A visible-light-induced difunctionalization of activated alkenes for building alkylsulfonylated oxindoles and amides through a radical Smiles rearrangement strategy was reported. A tandem SO2 insert/1,4-aryl migration/desulfonylation/cyclization sequence was involved in this... The content of this RSS Feed (c) The Royal Society of Chemistry

Source: RSC - Green Chem. latest articles - May 4, 2024 Category: Chemistry Authors: Si-Wei Tian Source Type: research