Structural Chemistry of Titanium (IV) Oxo Clusters, Part 2: Clusters Without Carboxylate or Phosphonate Ligands

Chemistry. 2024 Apr 17:e202400744. doi: 10.1002/chem.202400744. Online ahead of print.ABSTRACTHomometallic titanium oxo clusters (TOC) are one of the most important groups of metal oxo clusters. In a previous article, TOC structures with carboxylato and phosphonato ligands were reviewed and categorized. This work is now extended to clusters with other ligands. Comparison of the different cluster types shows how the interplay between condensation of the titanium polyhedra by means of bridging oxygen atoms and the coordination characteristics of the ligands influences the cluster structures and allows working out basic construction principles of the cluster core.PMID:38629948 | DOI:10.1002/chem.202400744

Source: Chemistry - April 17, 2024 Category: Chemistry Authors: Ulrich Schubert Berthold St öger Source Type: research