Multiple Force-Triggered Downconverted and Upconverted Emission in Polymers Containing Diels-Alder Adducts

Chem Asian J. 2024 Feb 9:e202301147. doi: 10.1002/asia.202301147. Online ahead of print.ABSTRACTFluorescent mechanophores can indicate the deformation or damage in polymers. The development of mechanophores with multi-triggered response is of great interest. Herein, Diels-Alder (DA) adducts are incorporated into linear poly(methyl acrylate) PMA-BA and network poly(hexyl methacrylate) (PHMA) as mechanophores to detect the stress caused by ultrasound, freezing, and compression. The DA mechanophores undergo retro-DA reaction to release 9-styrylanthracene chromophore upon applying force, resulting in cyan fluorescence. The dissociation ratio of the DA mechanophore after pulsed ultrasonication of PMA-BA solution for 240 minutes is estimated to be 52% by absorption spectra and 1H NMR. Additionally, the rate constant of mechanical cleavage is calculated to be 1.2×10-4 min-1·kDa-1 with the decrease in molecular weight from 69 to 22 kDa measured by gel permeation chromatography. Freezing of PHMA gels as well as compression of PHMA bulk samples turn-on the DA mechanophores, revealing the microscale fracture. Photon upconversion responses toward various force stimuli are also achieved in both polymer solutions and bulk samples by doping platinum octaethylporphyrin (PtOEP) or palladium meso-tetraphenyltetrabenzoporphyrin (PdTPTBP) sensitizers with multiple excitation wavelengths.PMID:38334040 | DOI:10.1002/asia.202301147

Source: Chemistry, an Asian Journal - February 9, 2024 Category: Chemistry Authors: Guohua Zhu Qiaoyu Zhang Tianjun Yu Jinping Chen Rui Hu Guoqiang Yang Yi Zeng Yi Li Source Type: research