CF3-Substituted Sulfonium Cations as Efficient Chalcogen Bond Donors towards Cyanometalates

This article is licensed under aCreative Commons Attribution-NonCommercial 3.0 Unported Licence.Tim-Niclas Streit, Rosa Maria Gomila, Robin Sievers, Antonio Frontera, Moritz Malischewski S-(CF3)thianthrenium and S-(CF3)dibenzothiophenium cations form potent chalcogen bonds (ChBs) with [Mo(CO)5CN]−, yielding S2N2 supramolecular motifs. Crystal structures reveal shorter S ···N contacts opposite the CF3 group compared to the aryl substituents.... The content of this RSS Feed (c) The Royal Society of Chemistry

Source: RSC - CrystEngComm latest articles - January 11, 2024 Category: Chemistry Authors: Tim-Niclas Streit Source Type: research