Heterometallic Ru-Ir carbonyl clusters as catalyst precursors for hydrogenation and hydrogen transfer reactions

This article is licensed under aCreative Commons Attribution-NonCommercial 3.0 Unported Licence.Francesca Forti, Cristiana Cesari, Marco Bortoluzzi, Cristina Femoni, Maria Carmela Iapalucci, Stefano Zacchini Reaction of [HRu3(CO)11] – (1) with [Ir(COD)Cl]2 in CH2Cl2 under H2 atmosphere afforded the dihydride [H2Ru3Ir(CO)12]– (2), which was quantitatively protonated to H3Ru3Ir(CO)12 (3) by strong acids such as HBF4·Et2O. The... The content of this RSS Feed (c) The Royal Society of Chemistry

Source: RSC - New J. Chem. latest articles - September 22, 2023 Category: Chemistry Authors: Francesca Forti Source Type: research