Synthesis of meso-pyrrole-substituted corroles by condensation of 1,9-diformyldipyrromethanes with pyrrole

Abstract
A copper triflate-mediated approach to access copper complexes of pyrrole-substituted corroles from the reaction of 1,9-diformyldipyrromethanes and an excess amount of pyrrole is presented for the first time. This procedure is a simple and efficient way for the preparation of corroles with a polymerizable substituent on meso-positions.

Beilstein J. Org. Chem. 2022, 18, 1403–1409. doi:10.3762/bjoc.18.145

Source: Beilstein Journal of Organic Chemistry - October 6, 2022 Category: Chemistry Authors: Beilstein Journal of Organic Chemistry - Syndicated Feeds Tags: corrole dipyrromethane macrocycles metal triflates pyrrole Full Research Paper Source Type: research