Titanium-Catalyzed Intermolecular Hydroaminoalkylation of Terminal Alkynes
Synthesis DOI: 10.1055/a-2111-9910 Terminal alkynes undergo intermolecular hydroaminoalkylation reactions with secondary amines in the presence of titanium catalysts and depending on the catalyst and the structure of the substrates, allylic amines and/or imines are formed as products in moderate yields. In addition, the desired allylamines can also be obtained from a convenient reaction sequence consisting of an initial hydroaminoalkylation of trimethylsilyl-protected alkynes and a subsequent protodesilylation that selectively delivers γ-unsubstituted allylamines. [...] Georg Thieme Verlag KG Rüdigerstraße 14, 70469 Stu...
Source: Synthesis - July 27, 2023 Category: Chemistry Authors: Thye, Hermann Fornfeist, Felix Geik, Dennis Schl üschen, Levi L. Schmidtmann, Marc Doye, Sven Tags: feature Source Type: research

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Synthesis 2023; 55: V- DOI: 10.1055/s-0040-1720080 Georg Thieme Verlag KG Rüdigerstraße 14, 70469 Stuttgart, GermanyArticle in Thieme eJournals: Table of contents (Source: Synthesis)
Source: Synthesis - July 27, 2023 Category: Chemistry Tags: table of contents Source Type: research

Activation of Diazo Compounds by Fluorinated Triarylborane Catalysts
Conclusions [...] Georg Thieme Verlag KG Rüdigerstraße 14, 70469 Stuttgart, GermanyArticle in Thieme eJournals: Table of contents  |  Abstract  |  open access Full text (Source: Synthesis)
Source: Synthesis - July 26, 2023 Category: Chemistry Authors: Pramanik, Milan Melen, Rebecca L. Tags: short review Source Type: research

Ni- and Pd-Catalyzed Enantioselective 1,2-Dicarbofunctionalization of Alkenes
Conclusion [...] Georg Thieme Verlag KG Rüdigerstraße 14, 70469 Stuttgart, GermanyArticle in Thieme eJournals: Table of contents  |  Abstract  |  Full text (Source: Synthesis)
Source: Synthesis - July 25, 2023 Category: Chemistry Authors: Kang, Taeho Apolinar, Omar Engle, Keary M. Tags: review Source Type: research

Synthetic Strategies for Accessing Dibenzophosphole Scaffolds
Conclusions [...] Georg Thieme Verlag KG Rüdigerstraße 14, 70469 Stuttgart, GermanyArticle in Thieme eJournals: Table of contents  |  Abstract  |  Full text (Source: Synthesis)
Source: Synthesis - July 25, 2023 Category: Chemistry Authors: Hattori, Hiroyuki Ishida, Kento Sakai, Norio Tags: review Source Type: research