Ultrasensitive detection of chloramphenicol in water using functionalized polymers with an Aluminium organic framework
Chemosphere. 2024 Apr 14:141981. doi: 10.1016/j.chemosphere.2024.141981. Online ahead of print.ABSTRACTMetal-Organic Frameworks (MOFs) are extensively used as electrode material in various sensing applications due to their efficacious porous nature and tunable properties. However, pristine MOFs lack conductive attributes that hinder their wide usage in electrochemical applications. Electropolymerization of several aromatic monomers has been a widely used strategy for preparing conducting electrode materials for various sensing applications in the past decades. Herein, we report a similar approach by employing the electropo...
Source: Chemosphere - April 16, 2024 Category: Chemistry Authors: Jithin Rafi Miriam Daniel Neppolian B Source Type: research

Radiation and male reproductive system: damage and protection
This article provides a review of radiation-induced damage to male reproduction, and the effects of damage mechanisms and pharmacotherapy. It is hoped that this review will contribute to the understanding of the effects of radiation on male reproduction, and provide information for research into drugs that can protect the reproductive health of males.PMID:38626814 | DOI:10.1016/j.chemosphere.2024.142030 (Source: Chemosphere)
Source: Chemosphere - April 16, 2024 Category: Chemistry Authors: Caimao Guo Qingyu Wang Peimeng Shuai Tiantian Wang Wenyu Wu Yuanyuan Li Shuqi Huang Jia Yu Lan Yi Source Type: research

Kinetics and Mechanism Analysis of Advanced Oxidation Degradation of PFOA/PFOS by UV/Fe < sup > 3+ < /sup > and Persulfate: A DFT Study
This study provides a DFT calculation process for the mechanism calculation of advanced oxidation degradation of other types of PFCs pollutants, hoping to elucidate the future development of PFCs removal. Further research should focus on determining the advanced oxidation degradation pathways of other types of PFCs, to support the development of computational studies on the advanced oxidation degradation of PFCs.PMID:38626815 | DOI:10.1016/j.chemosphere.2024.141951 (Source: Chemosphere)
Source: Chemosphere - April 16, 2024 Category: Chemistry Authors: Yilei Lai Ying Wang Shuyu Zhang Abing Duan Source Type: research

Degradation and humification of steroidal estrogens in the soil environment: a review
Chemosphere. 2024 Apr 14:142043. doi: 10.1016/j.chemosphere.2024.142043. Online ahead of print.ABSTRACTEmerging pollutants are toxic and harmful chemical substances characterized by environmental persistence, bioaccumulation and biotoxicity, which can harm the ecological environment and even threaten human health. There are four categories of emerging pollutants that are causing widespread concern, namely, persistent organic pollutants, endocrine disruptors, antibiotics, and microplastics. The distribution of emerging pollutants has spatial and temporal heterogeneity, which is influenced by factors such as geographical loc...
Source: Chemosphere - April 16, 2024 Category: Chemistry Authors: Qianhui Yang Weishan Liao Zebin Wei Rongliang Qiu Qian Zheng Qitang Wu Yangmei Chen Source Type: research

In-situ growth of Mn-Ni < sub > 3 < /sub > S < sub > 2 < /sub > on nickel foam for catalytic ozonation of p-nitrophenol
This study offers a new combination of supported catalysts with high efficiency and easy recovery, which provides a new idea for wastewater treatment.PMID:38626811 | DOI:10.1016/j.chemosphere.2024.142037 (Source: Chemosphere)
Source: Chemosphere - April 16, 2024 Category: Chemistry Authors: Linjie Zhu Siyi Zhou Hao Cheng Sridhar Komarneni Jianfeng Ma Source Type: research

Ecotoxicological Impact of Butisanstar and Clopyralid Herbicides on Soil Microbial Respiration and the Enzymatic Activities
This study provides a comprehensive assessment of the impact of butisanstar and clopyralid herbicides, both individually and in combination at different dosage (recommended field dose (RFD), ½, 2 and 5-times RFD). The assessment focuses on soil basal respiration (SBR), cumulative microbial respiration (CMR), and the activities dehydrogenase (DH), catalase (CAT), urease, acid and alkaline phosphatases (Ac-P and Alk-P) enzymes, along with their variations on days 10, 30, 60, and 90 post-herbicide application. Results indicate that, although herbicides, even at lower doses of RFD, demonstrate inhibitory effects on DH, CAT, a...
Source: Chemosphere - April 16, 2024 Category: Chemistry Authors: Tohid Rouhi-Kelarlou Ahmad Golchin Ali Ashraf Soltani Toularoud Source Type: research

Ultrasensitive detection of chloramphenicol in water using functionalized polymers with an Aluminium organic framework
Chemosphere. 2024 Apr 14:141981. doi: 10.1016/j.chemosphere.2024.141981. Online ahead of print.ABSTRACTMetal-Organic Frameworks (MOFs) are extensively used as electrode material in various sensing applications due to their efficacious porous nature and tunable properties. However, pristine MOFs lack conductive attributes that hinder their wide usage in electrochemical applications. Electropolymerization of several aromatic monomers has been a widely used strategy for preparing conducting electrode materials for various sensing applications in the past decades. Herein, we report a similar approach by employing the electropo...
Source: Chemosphere - April 16, 2024 Category: Chemistry Authors: Jithin Rafi Miriam Daniel Neppolian B Source Type: research

Radiation and male reproductive system: damage and protection
This article provides a review of radiation-induced damage to male reproduction, and the effects of damage mechanisms and pharmacotherapy. It is hoped that this review will contribute to the understanding of the effects of radiation on male reproduction, and provide information for research into drugs that can protect the reproductive health of males.PMID:38626814 | DOI:10.1016/j.chemosphere.2024.142030 (Source: Chemosphere)
Source: Chemosphere - April 16, 2024 Category: Chemistry Authors: Caimao Guo Qingyu Wang Peimeng Shuai Tiantian Wang Wenyu Wu Yuanyuan Li Shuqi Huang Jia Yu Lan Yi Source Type: research

Kinetics and Mechanism Analysis of Advanced Oxidation Degradation of PFOA/PFOS by UV/Fe < sup > 3+ < /sup > and Persulfate: A DFT Study
This study provides a DFT calculation process for the mechanism calculation of advanced oxidation degradation of other types of PFCs pollutants, hoping to elucidate the future development of PFCs removal. Further research should focus on determining the advanced oxidation degradation pathways of other types of PFCs, to support the development of computational studies on the advanced oxidation degradation of PFCs.PMID:38626815 | DOI:10.1016/j.chemosphere.2024.141951 (Source: Chemosphere)
Source: Chemosphere - April 16, 2024 Category: Chemistry Authors: Yilei Lai Ying Wang Shuyu Zhang Abing Duan Source Type: research

Degradation and humification of steroidal estrogens in the soil environment: a review
Chemosphere. 2024 Apr 14:142043. doi: 10.1016/j.chemosphere.2024.142043. Online ahead of print.ABSTRACTEmerging pollutants are toxic and harmful chemical substances characterized by environmental persistence, bioaccumulation and biotoxicity, which can harm the ecological environment and even threaten human health. There are four categories of emerging pollutants that are causing widespread concern, namely, persistent organic pollutants, endocrine disruptors, antibiotics, and microplastics. The distribution of emerging pollutants has spatial and temporal heterogeneity, which is influenced by factors such as geographical loc...
Source: Chemosphere - April 16, 2024 Category: Chemistry Authors: Qianhui Yang Weishan Liao Zebin Wei Rongliang Qiu Qian Zheng Qitang Wu Yangmei Chen Source Type: research

In-situ growth of Mn-Ni < sub > 3 < /sub > S < sub > 2 < /sub > on nickel foam for catalytic ozonation of p-nitrophenol
This study offers a new combination of supported catalysts with high efficiency and easy recovery, which provides a new idea for wastewater treatment.PMID:38626811 | DOI:10.1016/j.chemosphere.2024.142037 (Source: Chemosphere)
Source: Chemosphere - April 16, 2024 Category: Chemistry Authors: Linjie Zhu Siyi Zhou Hao Cheng Sridhar Komarneni Jianfeng Ma Source Type: research

Ecotoxicological Impact of Butisanstar and Clopyralid Herbicides on Soil Microbial Respiration and the Enzymatic Activities
This study provides a comprehensive assessment of the impact of butisanstar and clopyralid herbicides, both individually and in combination at different dosage (recommended field dose (RFD), ½, 2 and 5-times RFD). The assessment focuses on soil basal respiration (SBR), cumulative microbial respiration (CMR), and the activities dehydrogenase (DH), catalase (CAT), urease, acid and alkaline phosphatases (Ac-P and Alk-P) enzymes, along with their variations on days 10, 30, 60, and 90 post-herbicide application. Results indicate that, although herbicides, even at lower doses of RFD, demonstrate inhibitory effects on DH, CAT, a...
Source: Chemosphere - April 16, 2024 Category: Chemistry Authors: Tohid Rouhi-Kelarlou Ahmad Golchin Ali Ashraf Soltani Toularoud Source Type: research

Ultrasensitive detection of chloramphenicol in water using functionalized polymers with an Aluminium organic framework
Chemosphere. 2024 Apr 14:141981. doi: 10.1016/j.chemosphere.2024.141981. Online ahead of print.ABSTRACTMetal-Organic Frameworks (MOFs) are extensively used as electrode material in various sensing applications due to their efficacious porous nature and tunable properties. However, pristine MOFs lack conductive attributes that hinder their wide usage in electrochemical applications. Electropolymerization of several aromatic monomers has been a widely used strategy for preparing conducting electrode materials for various sensing applications in the past decades. Herein, we report a similar approach by employing the electropo...
Source: Chemosphere - April 16, 2024 Category: Chemistry Authors: Jithin Rafi Miriam Daniel Neppolian B Source Type: research

Radiation and male reproductive system: damage and protection
This article provides a review of radiation-induced damage to male reproduction, and the effects of damage mechanisms and pharmacotherapy. It is hoped that this review will contribute to the understanding of the effects of radiation on male reproduction, and provide information for research into drugs that can protect the reproductive health of males.PMID:38626814 | DOI:10.1016/j.chemosphere.2024.142030 (Source: Chemosphere)
Source: Chemosphere - April 16, 2024 Category: Chemistry Authors: Caimao Guo Qingyu Wang Peimeng Shuai Tiantian Wang Wenyu Wu Yuanyuan Li Shuqi Huang Jia Yu Lan Yi Source Type: research

Kinetics and Mechanism Analysis of Advanced Oxidation Degradation of PFOA/PFOS by UV/Fe < sup > 3+ < /sup > and Persulfate: A DFT Study
This study provides a DFT calculation process for the mechanism calculation of advanced oxidation degradation of other types of PFCs pollutants, hoping to elucidate the future development of PFCs removal. Further research should focus on determining the advanced oxidation degradation pathways of other types of PFCs, to support the development of computational studies on the advanced oxidation degradation of PFCs.PMID:38626815 | DOI:10.1016/j.chemosphere.2024.141951 (Source: Chemosphere)
Source: Chemosphere - April 16, 2024 Category: Chemistry Authors: Yilei Lai Ying Wang Shuyu Zhang Abing Duan Source Type: research