Using molten salts to probe outer-coordination sphere effects on lanthanide(III)/(II) electron-transfer reactions

Dalton Trans., 2021, Advance Article DOI: 10.1039/D1DT02708E, PaperMolly M. MacInnes, Zachary R. Jones, Bo Li, Nickolas H. Anderson, Enrique R. Batista, Ida M. DiMucci, Cecilia Eiroa-Lledo, Karah E. Knope, Maksim Y. Livshits, Stosh A. Kozimor, Veronika Mocko, Kristen A. Pace, Francisca R. Rocha, Benjamin W. Stein, Jennifer N. Wacker, Ping Yang Molten salt matrices were used to evaluate outer-coordination sphere effects on lanthanide redox chemistry. Results were rationalized by correlating the polarization power of the outer-sphere cation with shifts in the Ln3+/Ln2+ reduction potentials. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry
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