The effects of cellulose nanocrystal and cellulose nanofiber on the properties of pumpkin starch-based composite films

Int J Biol Macromol. 2021 Oct 1:S0141-8130(21)02115-2. doi: 10.1016/j.ijbiomac.2021.09.187. Online ahead of print.ABSTRACTPumpkin starch (PS) was extracted from Cucurbita maxima and utilized to prepare films in combination with cellulose nanocrystal (CNC) and cellulose nanofiber (CNF), using a solvent casting strategy. The PS was characterized to contain 26.6% of amylose, exhibiting a "B"-type crystalline structure and high stability against thermal degradation. PS/CNF films showed better thermal stability than PS/CNC films, whereas the CNC was more effective than CNF for enhancing the tensile strength (TS) of the films. The nanocomposite films containing 1% CNC showed the highest TS of 30.32 MPa. Fourier transform infrared spectra revealed stronger hydrogen bonding in the PS/CNC films, likely contributing to the observed high mechanical strength. CNC and CNF both decreased the transparency of PS films, by 5.2% and 13.1%, respectively. Overall, the properties of PS composite films can be effectively modified by incorporating CNC and CNF, as PS/CNC films with high mechanical strength and PS/CNF films with good thermal stability. Our results indicate that PS is a suitable material for CNC/CNF composite film fabrication. These films are expected to be especially useful in food packaging applications.PMID:34606791 | DOI:10.1016/j.ijbiomac.2021.09.187
Source: International Journal of Biological Macromolecules - Category: Biochemistry Authors: Source Type: research