Molecules, Vol. 26, Pages 2950: Triazolyl Conjugated (Oligo)Phenothiazines Building Blocks for Hybrid Materials —Synthesis and Electronic Properties

Molecules, Vol. 26, Pages 2950: Triazolyl Conjugated (Oligo)Phenothiazines Building Blocks for Hybrid Materials—Synthesis and Electronic Properties Molecules doi: 10.3390/molecules26102950 Authors: Hilla Khelwati Adam W. Franz Zhou Zhou Werner R. Thiel Thomas J. J. Müller The Cu-catalyzed alkyne-azide 1,3-dipolar cycloaddition variant provides a highly efficient entry to conjugated triazolyl-substituted (oligo)phenothiazine organosilicon derivatives with luminescence and reversible redox characteristics. Furthermore, by in-situ co-condensation synthesis several representative mesoporous MCM-41 type silica hybrid materials with embedded (oligo)phenothiazines are prepared and characterized with respect to their structural and electronic properties. The hybrid materials also can be oxidized to covalently bound embedded radical cations, which are identified by their UV/Vis absorption signature and EPR signals.
Source: Molecules - Category: Chemistry Authors: Tags: Article Source Type: research
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