Mechanistic insight into oxygen atom transfer reactions by mononuclear manganese(IV) –oxo adducts

Dalton Trans., 2021, Advance Article DOI: 10.1039/D0DT04436A, PaperPriya Singh, Eleanor Stewart-Jones, Melissa C. Denler, Timothy A. Jackson Rate enhancements in sulfoxidation reactions are often associated with a change in mechanism. Kinetic studies of sulfoxidation reactions by a series of MnIV–oxo complexes reveal large rate changes while retaining an oxygen-atom transfer mechanism. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry

Source: RSC - Dalton Trans. latest articles - February 23, 2021 Category: Chemistry Authors: Priya Singh Source Type: research