Pb(OF)Cu3(SeO3)2(NO3): a selenite fluoride nitrate with a breathing kagom é lattice.

Pb(OF)Cu3(SeO3)2(NO3): a selenite fluoride nitrate with a breathing kagomé lattice.
Chem Commun (Camb). 2020 Oct 14;56(80):11965-11968
Authors: Zhang M, Zhao Z, Zhang W, Li J, Huang X, He Z
Abstract
The Cu2+-based breathing kagomé material Pb(OF)Cu3(SeO3)2(NO3) with both corner-sharing and edge-sharing has been synthesized. Magnetic measurements suggest ferromagnetic interactions inside the layers and antiferromagnetic interactions between the neighboring layers, leading to an antiferromagnetic ground state with a field-induced spin-flip transition at low temperature.
PMID: 33033813 [PubMed]

Source: Chemical Communications - October 10, 2020 Category: Chemistry Authors: Zhang M, Zhao Z, Zhang W, Li J, Huang X, He Z Tags: Chem Commun (Camb) Source Type: research