Characterization in Aqueous Medium of an FMN Semiquinone Radical Stabilized by the Enzyme-Like Microenvironment of a Modified Polyethyleneimine

Org. Biomol. Chem., 2020, Accepted Manuscript DOI: 10.1039/D0OB00864H, CommunicationYoan Chevalier, Yvette Lock Toy Ki, Christian Herrero, Didier Le Nouen, Jean-Pierre Mahy, Jean-Philippe Goddard, Fr édéric Avenier The elusive flavin semiquinone intermediate found in flavoproteins such as cryptochromes has been obtained in aqueous solution by single electron reduction of the natural FMN cofactor using sodium ascorbate. This... The content of this RSS Feed (c) The Royal Society of Chemistry
Source: RSC - Organic and Biomolecular Chemistry - Category: Molecular Biology Authors: Source Type: research