A Hemilabile Manganese(I)-Phenol Complex and its Coordination Induced O –H Bond Weakening

Dalton Trans., 2020, Accepted Manuscript DOI: 10.1039/D0DT00973C, PaperKarthika J Kadassery, Matthew R. Crawley, Samantha N MacMillan, David C Lacy The known compound K[(PO)2Mn(CO)2] (PO = 2-((diphenylphosphino)methyl)-4,6-dimethylphenolate) (K[1]) was protonated to form the new Mn(I) complex (HPO)(PO)Mn(CO)2 (H1) and was determined to have a pKa approximately equal to tetramethylguanidine (TMG).... The content of this RSS Feed (c) The Royal Society of Chemistry

Source: RSC - Dalton Trans. latest articles - April 23, 2020 Category: Chemistry Authors: Karthika J Kadassery Source Type: research