Mn-Catalyzed Radical Initiated Domino Transformations of Alkynylated Cyclohexadienones with TMSN3 and O2 to Bicyclic Azido Alcohols

Chem. Commun., 2020, Accepted Manuscript DOI: 10.1039/D0CC00102C, CommunicationPranesh Pal, Prathama S Mainkar, Kiranmai Nayani, Srivari Chandrasekhar An efficient Mn-catalyzed cascade azide radical addition/cyclization/oxygen insertion reaction of alkyne-tethered cyclohexadienones with TMSN3 under mild conditions is reported. The domino reaction presents good diastereoselectivity generating bicyclic azido alcohol scaffolds... The content of this RSS Feed (c) The Royal Society of Chemistry

Source: RSC - Chem. Commun. latest articles - February 20, 2020 Category: Chemistry Authors: Pranesh Pal Source Type: research