Hydrogen generation: Aromatic dithiolate-bridged metal carbonyl complexes as hydrogenase catalytic site models.

Hydrogen generation: Aromatic dithiolate-bridged metal carbonyl complexes as hydrogenase catalytic site models.
J Inorg Biochem. 2014 Dec 3;143C:88-110
Authors: Pandey IK, Natarajan M, Kaur-Ghumaan S
Abstract
The design, syntheses and characteristics of metal carbonyl complexes with aromatic dithiolate linkers reported as bioinspired hydrogenase catalytic site models are described and reviewed. Among these the complexes capable of hydrogen generation have been discussed in detail. Comparisons have been made with carbonyl complexes having alkyl dithiolates as linkers between metal centers.
PMID: 25528677 [PubMed - as supplied by publisher]

Source: Journal of Inorganic Biochemistry - December 3, 2014 Category: Biochemistry Authors: Pandey IK, Natarajan M, Kaur-Ghumaan S Tags: J Inorg Biochem Source Type: research